Maybe this helps?
IHTM43035 - Inheritance Tax Manual - HMRC internal manual - GOV.UK (www.gov.uk)
This is catered for by IHTA84/S8B(2) which allows the personal representatives making a claim on the last death to include a claim on an earlier death, provided it will not affect the tax payable on that death. It follows that it must have been possible for a claim on be made on the earlier death – so the earlier death must have been on or after 9 October 2007.
Example
Roger died in July 2010. He had been predeceased by Jane who died in January 2008. She in turn had been predeceased by her first husband, Stephen, in 1997.
On Stephen’s death, he left his whole estate to Jane so that 100% of the nil rate band was unused. On Jane’s death she left her whole estate, valued at £270,000, on discretionary trusts for the children of her first marriage. As the estate was below the nil rate band, there was no need to make a claim to transfer the unused nil rate band from the first death.
On Roger’s death in July 2010, the amount of unused nil rate band available to transfer from Jane’s death is
Unused nil rate band calculation
M = £300,000
VT = £270,000
M* *is greater than VT by £30,000
Transferable nil rate band calculation
E =£30,000
NRBMD = £300,000 so
(30,000 ÷ 300,000) × 100 = 10.0000%
However, if Jane’s personal representatives had made a claim to transfer unused nil rate band from Stephen’s death, the actual nil rate band available on Jane’s death would have been £600,000. So the calculation becomes
Unused nil rate band calculation
M = £600,000
VT = £270,000
M* *is greater than VT by £330,000
Transferable nil rate band calculation
E =£330,000
NRBMD = £300,000 so
(330,000 ÷ 300,000) × 100 = 110.0000%
So the nil rate band available on Roger’s death is capped at 100% of the amount available at that time, giving a nil rate band of £650,000.